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产品名称：五氟苯甲酸甲酯
- 产品型号：36629-42-2
- 产品厂商：Ossila
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MSDS methyl-pentafluorobenzoate
Methyl pentafluorobenzoate (CAS number 36629-42-2) or methyl perfluorobenzoate is a fully fluorinated benzoic acid methyl ester. Methyl pentafluorobenzoate is used to synthesize linkers for graft polymers such as perfluorophenyl azide with N-hydroxysuccinimide end group (PFPA-NHS). To synthesize PFPA-NHS, it begins with a nucleophilic aromatic substitution of sodium azide to the para-position of ester. The hydrolysis of the ester is followed forming an azide perfluorobenzoic acid. The last step involves an EDC (1-ethyl-3-(3-dimethylaminopropyl)carbodiimide) catalyzed coupling reaction of N-hydroxysuccinimide and the carboxylic acid. PFPA-NHS has been used for preparing polyaniline grafted graphene and catalase grafted polycaprolactone.
After the hydrolysis of the ester group, methyl pentafluorobenzoate binds to cadmium for luminescence metal complexes with overall quantum yield up to 39%.
General Information
| CAS Number | 36629-42-2 |
| Chemical Formula | C8H3F5O2 |
| Full Name | Methyl pentafluorobenzoate |
| Molecular Weight | 226.10 g/mol |
| Synonyms |
Pentafluorobenzoic acid methyl ester, Perfluorobenzoic acid methyl ester, Methyl perfluorobenzoate |
| Classification / Family | Fluorinated building blocks, Aromatic building blocks, Graft polymer, Luminescence metal complexes |
Chemical Structure
Product Details
| Purity | 97% |
| Boiling Point | Tb = 223 °C at 760 mmHg |
| Relative Density | 1.53 g/mL at 25 °C |
| Appearance | Colorless liquid |