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简单介绍:
钙钛矿型固态电解质,室温锂离子电导率优异;缺点是易与金属锂发生还原反应,常被用于复合正极体系。
详情介绍:

Lithium lanthanum titanate (LLTO, CAS number: 12031-66-2) is a perovskite solid-state electrolyte. The general formula of LLTO is Li3xLa2/3-xTiO3, where x typically ranges from 0.05 to 0.33. The lithium and lanthanum contents impact the ionic conductivity and structural stability of the electrolyte. Increasing the lithium content generally enhances the ionic conductivity but can reduce structural stability. LLTO typically exhibits ionic conductivity in the range of 10−4 to 10−3 S/cm.

Lithium lanthanum titanate has been used in lithium sulfur batteries, all solid-state batteries, and supercapacitors. A lithium sulfur battery with a configuration of lithium/LLTO/polysulfide exhibits a high charge-storage capacity of 1429 mAh/g and electrochemical efficiency exceeding 99%. In solid-state capacitors, LLTO combined with 6% ionic liquid enables at least 10,000 charge–discharge cycles at an operating voltage of 2 V and a discharge current of 1.13 A/g (2 mA), achieving an outstanding Coulombic efficiency of 99%.


General Information


CAS Number 12031-66-2
Chemical Formula Li0.480La0.505TiO3
Full Name Lithium lanthanum titanium oxide
Molecular Weight 169.66 g/mol
Synonyms Lithium lanthanum perovskite, LLTO
Classification or Family Solid state electrolytes, Solid-state batteries, Lithium-iron batteries

Product Details


Ionic Conductivity 9.76 × 10−4 S/cm
Particle Size 1.05 µm (D50)
Specific Surface Area 2.62 m2/g
Appearance White powder


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