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2,5-Di-tert-butyl-1,4-dimethoxybenzene (DDB, CAS number 7323-63-9), an aromatic compound with two methoxy groups at 2,5-positions and two tert-butyl groups at 1,4-positions of the benzene ring, is a very successful benchmark redox shuttle molecule developed for the lithium ion battery (LIB) systems. With two tert-butyl groups, DDB has rigid molecular structure with an outstanding electrochemical reversibility and stability.
DDB provides high-rate overcharge protection of lithium iron phosphate (LiFePO4) based Li-ion cells by a reversible and stable redox reaction at 3.9 V vs. Li/Liand more than 200 cycles of 100% overcharge per cycle at C/2 and 1C rate for LiFePO+ 4 cathode in LIBs.
Despite being a benchmark shuttle, DDB has relatively low solubility in the carbonate electrolyte and the redox potential that is insufficient for 4 V operation of LIBs, due to its low polarity induced from symmetric structure.
General Information
| CAS Number | 7323-63-9 |
| Chemical Formula | C16H26O2 |
| Full Name | 1,4-Di-tert-butyl-2,5-dimethoxybenzene |
| Molecular Weight | 250.38 g/mol |
| Synonyms |
DDB, 2,5-Di-tert-butyl-1,4-dimethoxybenzene, 1,4-Di-t-butyl-2,5-dimethoxybenzene; |
| Classification / Family |
Redox Shuttle, Battery materials, Energy materials, Lithium ion batteries (LLIBs) |
Chemical Structure
Product Details
| Purity | >99% (GC) |
| Melting Point | 103-104 °C |
| Appearance | White to off-white powder |
