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PCBM in its full form is [6,6] phenyl-C61-butyric acid methyl ester. The butyric acid methyl ester and phenyl functionality means it is a solubilized version of the buckminsterfullerene, C60.
PCBM is one of the most commonly used electron accepting materials in organic photovoltaic devices. It is also used as an electron transport material in bulk heterojunction perovskite-PCBM solar cells. The solubility enables PCBM to be dissolved in common solvents used for donor polymers, allowing the simultaneous casting of polymer and fullerene and the formation of an efficient bulk heterojunction. When used in a device with a donor polymer, PCBM enables rapid and efficient charge transfer and exciton dissociation[1], and has a high electron mobility[2].
The 99% purity PCBM is recommended for general OPV use, and the 99.5% purity PCBM is recommended for OFET applications where the highest crystallization and mobility is required.
General Information
Please note: The product code M111 has been updated to M0111.
| CAS Number | 160848-22-6 |
|---|---|
| Chemical Formula | C72H14O2 |
| Full Name | [6,6]-Phenyl-C61-butyric acid methyl ester |
| Molecular Weight | 911 g/mol |
| HOMO / LUMO | HOMO = -6.1 eV, LUMO = -3.7 eV |
| Synonyms | C60PCBM, PC60BM, PC61BM, [60]PCBM, 3’H-cyclopropa[1,9][5,6]fullerene-C60-Ih-3′-butanoic acid 3′-phenyl methyl ester |
| Classification or Family | Fullerenes, Organic semiconducting materials, Organic Photovoltaics, Polymer Solar Cells, Perovskite Solar cells, OFETs, Electron transport layer materials |
