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P(g2T-TT) is a copolymer with a backbone alternating thienothiophene (TT) and 2,2'-bithiophene (BT) units with triethylene glycol (TEG) side chains in the 3,3′ positions of the bithiophene repeating units. The triethylene glycol side chains can facilitate hydration and ion penetration without compromising electronic mobility by shifting the mode of operation of aqueous electrolyte-gated transistors from interfacial to bulk doping/transport.
With triethylene glycol side chains, P(g2T-TT) films can uptake a much higher density of ions while showing a much lower degree of hydration than PEDOT:PSS films. The P(g2T-TT) films can also show a high degree of molecular ordering during electrochemical switching, demonstrating complete and reversible electrochromism and high volumetric capacitance at low operating biases. Bulk doping of P(g2T-TT) by hydrated ions allows for extraction of the volumetric capacitance of C*=240 F/cm3, a value almost six times higher than that of PEDOT:PSS, indicating a higher density of ion-accessible sites.
The Luminosyn™ Range
General Information
| CAS Number | 2058240-28-9 |
|---|---|
| Full Name | Poly[2-(3,3′-bis(2-(2-(2-methoxyethoxy)ethoxy)ethoxy)-[2,2’-bithiophen]-5-yl)thieno[3,2-b]thiophene] |
| Chemical Formula | (C28H34O8S4)n |
| HOMO/LUMO | HOMO = 5.2 eV (Eg = 1.74 eV) [1] |
| Absorption | λmax = 597 nm (in film) |
| Form | Blue powder/fibers |
| Processing Solvents | DMF, Chloroform (typically 5 mg/ml in chloroform) |
| Synonyms | pg2T-TT, g2T-TT |
| Classification / Family | Polythiophenes, Redox-active semiconducting polymer (RASP), Organic electrochemical transistors (OECTs), Electrocardiogram (ECG) recording, Biosensors |
