N-羟基邻苯二甲酰亚胺|524-38-9 524-38-9
产品简介
N-羟基邻苯二甲酰亚胺|524-38-9由中国密思通试剂导购网品质提供,可查询价格,在线订购。提供技术资料。定制合成和大包装,是专业**试剂生产及供应商。欢迎拨打021-51672891/51672892洽谈选购,更多产品请登录www.chemmis.com
产品详细信息
N-Hydroxyphthalimide, 98+%N-羟基邻苯二甲酰亚胺, 98+%
CAS | 524-38-9 | MDL | MFCD00005891 | EINECS: | 208-358-1 | ||
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Not regulated for shipping | |||||||
别名: | NHPI |
化学性质
分子式: | C8H5NO3 | 熔点: | ca 233° dec. | |
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分子量: | 163.13 |
参考文献
Additive in the carbodiimide method of peptide coupling, leading to decreased racemization: J. Am. Chem. Soc., 89, 7151 (1967). For alternative reagents, see N,N'-Dicyclohexylcarbodiimide, A10973, and Appendix 6.
O-Alkylation followed by hydrazinolysis gives O-alkylhydroxylamines: Bull. Soc. Chim. Fr., 833 (1976). Copper-promoted coupling with arylboronic acids, followed by hydrazinolysis, affords O-arylhydroxylamines: Org. Lett., 3, 139 (2001).
Efficient electron carrier for electrochemical oxidation of alcohols: J. Chem. Soc., Chem. Commun., 479 (1983). Has also been found to be an efficient catalyst for non-electrochemical oxidation of benzylic groups in benzonitrile solution with atmospheric pressure oxygen: J. Org. Chem., 60, 3934 (1995). The method can be extended to alkanes by the use of a catalyst such as 0.5-1 mol% Co(acac)2. Thus cyclohexane is oxidized to cyclohexanone and adipic acid; adamantane gives mainly 1-adamantanol with minor amounts of 2-adamantanone and 1,3-adamantanediol: J. Org. Chem., 61, 4520 (1996). Under similar conditions alkynes can be oxygenated to ɑß-acetylenic ketones in good yields: Chem. Commun., 2037 (1998).
其他参考资料
Merck: | 14,4838 |
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Beilstein: | 131208 |
危险与**
危险等级 : | 36/37/38 |
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Irritating to eyes, respiratory system and skin. | |
**等级 : | 26-37 |
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable gloves. | |
TSCA: | 是 |
RTECS: | TI5200000 |